I would like to have with pleasure Talia's head as a PC and could also isolate him like you see in the Screenshot:
http://img146.imageshack.us/i/unbenanntgi.jpg/)
But how does it go on now and is this generally possible?
Unfortunately, Talia's is a full body model. This means that the head is in one single model with the body. While it is possible to hide the head from the model and use that model as a clothing or armor, its impossible to do it with the head of a full body.
For example, I wouldn't be able to take away Atris' robes, and just use her head (although there is already a head in game that has some resemblance of Atris.)
Sorry, but the closest thing you'll get to a Talia head is skinning a new head that looks like hers.